W G Frankenburg; V I Komarewsky; Eric K Rideal's Advances in catalysis PDF

By W G Frankenburg; V I Komarewsky; Eric K Rideal

ISBN-10: 0080565077

ISBN-13: 9780080565071


content material: entrance conceal; Advances in Catalysis and similar matters, quantity III; Copyright web page; Contents; individuals to quantity III; Editors' Preface; bankruptcy 1. Balandin's Contribution to Heterogeneous Catalysis; I. advent; II. The Multiplet conception; III. dialogue of the speculation; IV. Steric concerns in Catalysis; References; bankruptcy 2. Magnetism and the constitution of Catalytically energetic Solids; I. creation; II. normal rules; III. Experimental equipment; IV. The Susceptibility Isotherm; V. Supported Chromium Oxide; VI. Supported Oxides of Manganese; VII. Supported Nickel Oxide VIII. Supported Iron OxideIX. Supported Copper Oxide; X. comparable platforms; XI. Self-Supported platforms; XII. Ferromagnetism; XIII. id of Ferromagnetic stages; XIV. response strategies; XV. resolution tactics; XVI. precis; References; bankruptcy three. Catalytic Oxidation of Acetylene in Air for Oxygen Manufacture; I. creation; II. of Air and Acetylene; III. Acetylene removing; IV. Catalyst Compositions; V. Regeneration; VI. Mechanism of the Oxidation Reactions; VII. Mechanism of the Oxidation by means of Silver Nitrate; References; bankruptcy four. The Poisoning of metal Catalysts I. Catalysts at risk of PoisoningII. imperative different types of Catalyst Poisons; III. the shape of Catalyst Poisoning Curves; IV. additional elements Influencing Toxicity; V. important Poisoning; References; bankruptcy five. Catalytic Cracking of natural Hydrocarbons; I. creation; II. Catalytic Cracking Reactions; III. Catalytic Cracking of Paraffins; IV. Catalytic Cracking of Olefins; V. Catalytic Cracking of Naphthenes; VI. Catalytic Cracking of fragrant Hydrocarbons; VII. constitution of Cracking Catalysts; References; bankruptcy 6. Chemical features and constitution of Cracking Catalysts I. IntroductionII. dimension of the "Acidity" of Cracking Catalysts; III. identity of the Acid facilities because the Catalytically energetic websites; IV. constitution of the Acid; V. Mechanism of Hydrocarbon Reactions on a Cracking Catalyst; References; bankruptcy 7. response premiums and Selectivity in Catalyst Pores; I. creation; III . The actual photo of the Pore constitution; III. Mechanism of shipping in Catalyst Pores; IV. actual elements picking out response premiums on Porous Catalysts . (Definition of fee Constants, the elemental Differential Equation and the legislations of Conservation of Mass V. response charges in unmarried PoresVI. response premiums on sensible Catalyst Pellets; VII. response charges on Poisoned Catalysts (Apparent Selective Poisoning); VIII. impression of Pore constitution on Catalyst Selectivity; Appendix; word list of Symbols; References; bankruptcy eight. Nickel Sulfide Catalysts; I. advent; II. The Nickel-Sulfur Equilibrium; III. actual Adsorption of Gases on Ni2S2 Catalysts; IV. Chemisorption of Gases on Ni2S2; V. helps for Stabilizing Nickel Sulfide; VI. instruction of Nickel Sulfide Catalysts; VII. valuable existence and Regeneration
summary: ADVANCES IN CATALYSIS quantity three

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1. Preparation.. . . . . ............................ 2. Susceptibility Data.. . IX. Supported Copper Oxide.. 1. Preparation.. 2. Susceptibility Data. ............................ 3. Activity Data . . . . . . . . . . . . . . . . . . . . . . . . . X. Related Systems . . . . . . . . . . . . . . . . . . . . . . . . . XI. Self-supported Systems. 1. Introduction . . . . . . . .

1. Preparation . . . . . . . . . . . . . . . . . . . . . . . ...................... 4. Activity Data . . . . . . . . . . . . . . . . . . . . . . . . . VIII. Supported Iron Oxide.. . . . . . . . . . . . . . . . . . . . . . . 1. Preparation.. . . . . ............................ 2. Susceptibility Data.. . IX. Supported Copper Oxide.. 1. Preparation.. 2. Susceptibility Data. ............................

This more than covers the range of concentrations found in the industrial use of this catalyst. Analysis of each catalyst sample for chromium content was carried out as follows: The samples were brought into solution by sodium peroxide fusion. The melt was dissolved in water and the solution was boiled to decompose the excess peroxide. After acidification of the solution with sulfuric and phosphoric acids, an excess of ferrous ammonium sulfate was added, and the excess was titrated with dichromate solution, with the use of barium diphenylamine sulfonate as indicator.

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Advances in catalysis by W G Frankenburg; V I Komarewsky; Eric K Rideal

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